Substance
ID:180149
Names and Identifiers
Synonyms
Di-tert-butyl azodiformateNSC 109889DBADDi-tert-butyl azodicarboxylate偶氮二甲酸二叔丁酯Bis(1,1-dimethylethyl)azodicarboxylate
IUPAC name
(E)-N-{[(tert-butoxy)carbonyl]imino}(tert-butoxy)formamide
IUPAC Traditional name
(E)-N-[(tert-butoxycarbonyl)imino](tert-butoxy)formamide
Registration numbers
CAS Number
MDL Number
Beilstein Number
EC Number
Properties
Safety Information
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
GHS Signal Word
Warning
European Hazard Symbols
Irritant (Xi)GHS Precautionary statements
P261-P305+P351+P338
Safety Statements
26-36
Risk Statements
36/37/38
German water hazard class
3
GHS Hazard statements
H315-H319-H335
Molecule Details
Application
Reactant for:
• Preparation of hexapeptide key fragments via stereoselective selenocyclization/oxidative deselenylation or hydrazination/cyclization reactions1
• Asymmetric Michael addition reactions2
• Preparation of dipeptidyl peptidase IV dependent water-soluble prodrugs via Mitsunobu reaction3
• Synthesis of pyrroloisoquinoline template via stereoselective N-acyliminium-mediated cyclization and enolate amination for synthesis of peptidomimetic compounds4
• Barbier-type propargylation reactions5
• Synthesis of bacterial peptide deformylase (PDF) inhibitor fumimycin6
• Asymmetric amination of glycine Schiff bases7
Reactant for:
• Preparation of hexapeptide key fragments via stereoselective selenocyclization/oxidative deselenylation or hydrazination/cyclization reactions1
• Asymmetric Michael addition reactions2
• Preparation of dipeptidyl peptidase IV dependent water-soluble prodrugs via Mitsunobu reaction3
• Synthesis of pyrroloisoquinoline template via stereoselective N-acyliminium-mediated cyclization and enolate amination for synthesis of peptidomimetic compounds4
• Barbier-type propargylation reactions5
• Synthesis of bacterial peptide deformylase (PDF) inhibitor fumimycin6
• Asymmetric amination of glycine Schiff bases7
Molecular Spectra
No Data Available
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References
No Data Available
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