Substance
ID:180114
Names and Identifiers
IUPAC name
triphenyl[3-(trimethylsilyl)prop-2-yn-1-yl]phosphanium bromide
Synonyms
(3-Trimethylsilyl-2-propynyl)triphenylphosphonium bromide(3-三甲基硅基-2-丙炔基)三苯基溴化磷
IUPAC Traditional name
triphenyl[3-(trimethylsilyl)prop-2-yn-1-yl]phosphanium bromide
Properties
Safety Information
Risk Statements
36/37/38
GHS Signal Word
Warning
GHS Hazard statements
H315-H319-H335
GHS Precautionary statements
P261-P305+P351+P338
Storage Temperature
2-8°C
German water hazard class
3
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
European Hazard Symbols
Irritant (Xi)Safety Statements
26-36
Molecule Details
Application
Reactant for:
• Horner-Wadsworth-Emmons olefination1
• Aromatic ring umpolung2
• Stereoselective Wittig reaction3
• Bromoetherification reactions4
• Olefination of Garner′s aldehyde5
• Regioselective Wittig reaction6
Reactant for:
• Horner-Wadsworth-Emmons olefination1
• Aromatic ring umpolung2
• Stereoselective Wittig reaction3
• Bromoetherification reactions4
• Olefination of Garner′s aldehyde5
• Regioselective Wittig reaction6
Molecular Spectra
No Data Available
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References
No Data Available
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