CAS 75-25-2|Tribromomethane|tribromomethane|bromoform|BROMOFORM|Methenyl tribromide|Bromoform|Methyl tribromide|Tribromomethane|三溴甲烷|Bromoform|Tribromomethane 97%|溴仿

InChI=1S/CHBr3/c2-1(3)4/h1H

DIKBFYAXUHHXCS-UHFFFAOYSA-N

H Acceptors

H Donor

LogD (pH = 5.5)

2.276419

LogD (pH = 7.4)

2.276419

Log P

2.276419

Molar Refractivity

29.7928

Polarizability

12.047271

Polar Surface Area

0.0

Rotatable Bonds

Lipinski's Rule of Five

true

Log P

2.5

LOG S

-2.13

Solubility (Water)

1.88e+00 g/l

TribromomethaneBROMOFORMMethyl tribromideMethenyl tribromideBromoformTribromomethane三溴甲烷BromoformTribromomethane 97%溴仿

IUPAC Traditional name

Unique Ingredient Identifier

Toxic/Irritant/Lachrymatory/Light Sensitive

Light Sensitive

PB5600000

Toxic (T)

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CHBr3

1-3% ethanol as stabilizer

60-120 ppm 2-methyl-2-butene as stabilizer

~0.05% amylene as stabilizer

~1% ethanol as stabilizer

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DB03054

Drug information: experimental

OR17912

Stabilised with ethanol

05202320

MP Biomedicals Rare Chemical collection

132942

Packaging
1 kg in glass bottle
250 g in glass bottle

241032

Packaging
50, 250 g in glass bottle

• For examples of the generation of dibromocarbene, using Potassium tert-butoxide, A13947, as base, see: Org. Synth. Coll., 6, 187 (1988); 7, 200 (1990). Alternatively, reactions can be carried out with aqueous OH^- and a phase-transfer catalyst such as Benzyltriethylammonium chloride, A13268: Org. Synth. Coll., 8, 223 (1993), or using crown ether catalysis: Org. Synth., 75, 98 (1997).

• Under phase-transfer conditions, allylic bromides undergo nucleophilic displacement by the tribromomethyl anion: J. Chem. Soc., Chem. Commun., 210 (1979).

Names and Identifiers

Synonyms

TribromomethaneBROMOFORMMethyl tribromideMethenyl tribromideBromoformTribromomethane三溴甲烷BromoformTribromomethane 97%溴仿

IUPAC Traditional name

bromoform

IUPAC name

tribromomethane

Registration numbers

CAS Number

75-25-2

Beilstein Number

1731048

PubChem SID

2486301446508715248720672484808516096620624854456

MDL Number

EC Number

PubChem CID

CHEMBL

Chemspider ID

MeSH Name

DrugBank ID

Unique Ingredient Identifier

Wikipedia Title

CHEBI ID

Gmelin ID

KEGG ID

Merck Index

Molecule Details

DB03054

Drug information: experimental

Apollo Scientific

OR17912

Stabilised with ethanol

MP Biomedicals

05202320

MP Biomedicals Rare Chemical collection

Wikipedia

Bromoform

Sigma Aldrich

132942

Packaging
1 kg in glass bottle
250 g in glass bottle

241032

Packaging
50, 250 g in glass bottle

References

PubChem Literature

From Data Sources

• Under phase-transfer conditions, allylic bromides undergo nucleophilic displacement by the tribromomethyl anion: J. Chem. Soc., Chem. Commun., 210 (1979).

Bioactivity

PubChem BioAssay

Nature polluting (N)

LD50

933.0 mg kg^-1 (oral, rat)

GHS Signal Word

DANGER

Danger

NFPA704

EU Index

602-007-00-X

UN Number

2515

UN2515

GHS Pictograms

Acute toxicity (oral, dermal, inhalation), categories 1,2,3

Hazardous to the aquatic environment

Acute hazard, category1

Chronic hazard, categories 1,2

Acute toxicity (oral, dermal, inhalation), categories 1,2,3

Hazardous to the aquatic environment

Acute hazard, category1

Chronic hazard, categories 1,2

Respiratory sensitization, category 1

Germ cell mutagenicity, categories 1A,1B,2

Carcinogenicity, categories 1A,1B,2

Reproductive toxicity, categories 1A,1B,2

Specific Target Organ Toxicity – Single exposure, categories 1,2

Specific Target Organ Toxicity – Repeated exposure, categories 1,2

Aspiration Hazard, category 1

GHS Hazard statements

302,315,319,331,411

H302-H315-H319-H331-H411

H331-H302-H315-H319-H351-H411

GHS Precautionary statements

261,273,305+351+338,311

P261-P273-P305+P351+P338-P311

P261-P305+P351+P338-P302+P352-P321-P405-P501A

RID/ADR

UN 2515 6.1/PG 3

Hazard Class

6.1

Personal Protective Equipment

Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Packing Group

III

German water hazard class

Storage Temperature

2-8°C

TSCA Listed

是

Grade

puriss.

purum

analytical standard, for environmental analysis

analytical standard

Quality

amylene stabilized

Packaging

ampule of 5000 mg

Std enthalpy of combustion

Partition Coefficient

Std enthalpy of formation

European Hazard Symbols

Certificate of Analysis

Empirical Formula (Hill Notation)

Molecule

ID:2758