CAS 594-09-2|Trimethylphosphane (substitutive)<br />Trimethylphosphorus (additive)|trimethylphosphane|trimethylphosphine|三甲基膦|Trimethylphosphorus|Trimethylphosphine|Trimethylphosphine|三甲基膦 ...

InChI=1S/C3H9P/c1-4(2)3/h1-3H3

YWWDBCBWQNCYNR-UHFFFAOYSA-N

LogD (pH = 7.4)

0.38

LogD (pH = 5.5)

0.16

Log P

1.06

Rotatable Bonds

H Donor

H Acceptors

Lipinski's Rule of Five

true

Acid pKa

8.38

Polar Surface Area

0.00

Polarizability

8.32

Molar Refractivity

26.66

LOG S

2.09

IUPAC Systematic name

Trimethylphosphane (substitutive)
Trimethylphosphorus (additive)

IUPAC Traditional name

三甲基膦TrimethylphosphorusTrimethylphosphine三甲基膦溶液TrimethylphosphinePMe3Trimethylphosphine solutionMethyl phosphine(CH3)3Ptrimethylphosphinetrimethylphosphinetrimethyl phosphineMe3PPMe3

DANGER

Danger

S9,S16,S26,S36/37/39

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324108

Application
Reagent used in Mitsunobu reaction; transformation of azides into carbamates, aziridines from azidoalcohols; iminophosphoranes and aza-Wittig reaction.
Packaging
100 mL in Sure/Seal™

323322

Application
Electron-rich phosphine ligand used in numerous applications such as cross-coupling reactions.
Reagent used in Mitsunobu reaction; transformation of azides into carbamates, aziridines from azidoalcohols; iminophosphoranes and aza-Wittig reaction.
Packaging
25 g in Sure/Seal™

324116

Application
Reagent used in Mitsunobu reaction; transformation of azides into carbamates, aziridines from azidoalcohols; iminophosphoranes and aza-Wittig reaction.
Packaging
100 mL in Sure/Seal™

92725

Other Notes
Widely used ligand in transition metal complexes1

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Names and Identifiers

IUPAC Systematic name

Trimethylphosphane (substitutive)
Trimethylphosphorus (additive)

IUPAC name

trimethylphosphane

IUPAC Traditional name

trimethylphosphine

Synonyms

Registration numbers

EC Number

MDL Number

Beilstein Number

CAS Number

PubChem SID

24859357248594232485942416222429914718322

Chemspider ID

CHEBI ID

Wikipedia Title

PubChem CID

MeSH Name

Patent number

EP1982988EP1882690WO2005010028WO2005075462EP1537913WO2006127893WO2005100367WO2005051875EP1953171WO2006043121EP1690552WO2008125207

ACToR Database

SureChEMBL Database

NMRShiftDB Database

CompTox Database

Molecule Details

324108

Application
Reagent used in Mitsunobu reaction; transformation of azides into carbamates, aziridines from azidoalcohols; iminophosphoranes and aza-Wittig reaction.
Packaging
100 mL in Sure/Seal™

323322

324116

Application
Reagent used in Mitsunobu reaction; transformation of azides into carbamates, aziridines from azidoalcohols; iminophosphoranes and aza-Wittig reaction.
Packaging
100 mL in Sure/Seal™

92725

Other Notes
Widely used ligand in transition metal complexes1

Wikipedia

Trimethylphosphine

References

PubChem Literature

No Data Available

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Bioactivity

PubChem BioAssay

9-16-26-36/37/39

26-36/37/39-45

GHS Pictograms

Acute toxicity (oral, dermal, inhalation), category 4

Skin irritation, category 2

Eye irritation, category 2

Skin sensitisation, category 1

Specific Target Organ Toxicity – Single exposure, category 3

Flammable gases, category 1

Flammable aerosols, categories 1,2

Flammable liquids, categories 1,2,3

Self-reactive substances and mixtures, Types B,C,D,E,F

Pyrophoric liquids, category 1

Pyrophoric solids, category 1

Self-heating substances and mixtures

Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3

Organic peroxides, Types B,C,D,E,F

Flammable gases, category 1

Flammable aerosols, categories 1,2

Flammable liquids, categories 1,2,3

Self-reactive substances and mixtures, Types B,C,D,E,F

Pyrophoric liquids, category 1

Pyrophoric solids, category 1

Self-heating substances and mixtures

Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3

Organic peroxides, Types B,C,D,E,F

Acute toxicity (oral, dermal, inhalation), category 4

Skin irritation, category 2

Eye irritation, category 2

Skin sensitisation, category 1

Specific Target Organ Toxicity – Single exposure, category 3

Respiratory sensitization, category 1

Germ cell mutagenicity, categories 1A,1B,2

Carcinogenicity, categories 1A,1B,2

Reproductive toxicity, categories 1A,1B,2

Specific Target Organ Toxicity – Single exposure, categories 1,2

Specific Target Organ Toxicity – Repeated exposure, categories 1,2

Aspiration Hazard, category 1

Corrosive to metals, category 1

Skin corrosion, categories 1A,1B,1C

Serious eye damage, category 1

UN Number

1993

UN2845

European Hazard Symbols

Irritant (Xi)

Flammable (F)

Harmful (Xn)

Corrosive (C)

GHS Precautionary statements

210,261,305+351+338

P210-P261-P281-P301+P310-P331

P210-P261-P305+P351+P338

P210-P303+P361+P353-P305+P351+P338-P405-P422A-P501A

GHS Hazard statements

225,315,319,335

H225-H304-H315-H336-H361d-H373

H225-H315-H319-H335

H225-H250-H252-H314-H318

RID/ADR

UN 1993 3/PG 2

German water hazard class

Packing Group

Personal Protective Equipment

Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)

Hazard Class

4.2

Storage Temperature

2-8°C

Supplemental Hazard Statements

May form explosive peroxides.

TSCA Listed

否

Storage Warning

Air & Moisture Sensitive

Molecule

ID:130013