CAS 3277-26-7|dimethylsilyl ether|[(dimethylsilyl)oxy]dimethylsilane|1,1,3,3-TETRAMETHYLDISILOXANE|1,1,3,3-四甲基二硅氧烷|1,1,3,3-Tetramethyldisiloxane|Siloxane HSi2|四甲基二氢二硅氧烷|1,1,3,3-四甲基...

General Information

Structure

Molecular Formula

C₄H₁₄OSi₂

Molecular Mass

134.32436

Exact Mass

134.05831813

Charge

InChI

InChI=1S/C4H14OSi2/c1-6(2)5-7(3)4/h6-7H,1-4H3

InChIKey

NVYQDQZEMGUESH-UHFFFAOYSA-N

Canonic Smiles

C[SiH](O[SiH](C)C)C

Isomeric Smiles

C[SiH](C)O[SiH](C)C

Calculated Properties

JChem

H Acceptors

H Donor

LogD (pH = 5.5)

-0.1864

LogD (pH = 7.4)

-0.1864

Log P

-0.1864

Molar Refractivity

26.0706

Polarizability

14.659903

Polar Surface Area

9.23

Rotatable Bonds

Lipinski's Rule of Five

true

Data Source

Names and Identifiers

IUPAC Traditional name

dimethylsilyl ether

IUPAC name

[(dimethylsilyl)oxy]dimethylsilane

Synonyms

1,1,3,3-TETRAMETHYLDISILOXANE1,1,3,3-四甲基二硅氧烷1,1,3,3-TetramethyldisiloxaneSiloxane HSi2四甲基二氢二硅氧烷1,1,3,3-四甲基二甲硅醚

Names and Identifiers

Registration numbers

CAS Number

3277-26-7

MDL Number

MFCD00008256

PubChem SID

16209797524900267248887432488932124853998

PubChem CID

6327482

EC Number

221-906-4

Beilstein Number

1733364

Registration numbers

Properties

Related Proteins

No Data Available

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Molecular Spectra

No Data Available

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Molecule Details

MP Biomedicals

05225814

MP Biomedicals Rare Chemical collection

Sigma Aldrich

235733

Packaging
25, 100 g in glass bottle

92231

Other Notes
prices for bulk quantities on request
Packaging
500 g in glass bottle

87835

Other Notes
Reducing agent1,2,3

Molecule Details

References

PubChem Literature

From Data Sources

• With a Pd(0) catalyst, acetylenes are reduced to olefins (mainly cis): Tetrahedron Lett., 30, 4675 (1989).

• Forms polymers via hydrosilylation of alkadienes and and alkynes.

• Reducing agent:

• In the presence of TMS chloride and either LiBr or NaI, aromatic aldehydes are reduced directly to benzyl halides: Tetrahedron Lett., 25, 1103 (1984).

• In the presence of a catalytic amount of titanium isopropoxide, secondary and tertiary phosphine oxides can be reduced to the corresponding phosphines in high yield, avoiding pyrophoric reagents: Synlett, 1545 (2007).

References

Bioactivity

PubChem BioAssay

Bioactivity

Names and Identifiers

IUPAC Traditional name

dimethylsilyl ether

IUPAC name

[(dimethylsilyl)oxy]dimethylsilane

Synonyms

1,1,3,3-TETRAMETHYLDISILOXANE1,1,3,3-四甲基二硅氧烷1,1,3,3-TetramethyldisiloxaneSiloxane HSi2四甲基二氢二硅氧烷1,1,3,3-四甲基二甲硅醚

Registration numbers

CAS Number

3277-26-7

MDL Number

MFCD00008256

PubChem SID

16209797524900267248887432488932124853998

PubChem CID

EC Number

Beilstein Number

Molecule Details

MP Biomedicals Rare Chemical collection

Sigma Aldrich

235733

Packaging
25, 100 g in glass bottle

92231

Other Notes
prices for bulk quantities on request
Packaging
500 g in glass bottle

87835

Other Notes
Reducing agent1,2,3

References

PubChem Literature

From Data Sources

• With a Pd(0) catalyst, acetylenes are reduced to olefins (mainly cis): Tetrahedron Lett., 30, 4675 (1989).

• Forms polymers via hydrosilylation of alkadienes and and alkynes.

• Reducing agent:

• In the presence of TMS chloride and either LiBr or NaI, aromatic aldehydes are reduced directly to benzyl halides: Tetrahedron Lett., 25, 1103 (1984).

Bioactivity

PubChem BioAssay

Properties

Molecule

ID:112784