CAS 7787-70-4|copper(1+) bromide|CUPROUS BROMIDE|$l^{1}-copper(1+) ion bromide|Copper(I) bromide|Copper(I) bromide, Puratronic®|溴化亚铜(I)|λ<sup>1</sup>-copper(1+) ion bromide|溴化亚铜(I), Pur...

General Information

Structure

Molecular Formula

BrCu

Molecular Mass

143.45

Exact Mass

141.8479345

Charge

InChI

InChI=1S/BrH.Cu/h1H;/q;+1/p-1

InChIKey

NKNDPYCGAZPOFS-UHFFFAOYSA-M

Canonic Smiles

[Cu+].[Br-]

Isomeric Smiles

[Cu+].[Br-]

Calculated Properties

JChem

H Acceptors

H Donor

LogD (pH = 5.5)

0.156

LogD (pH = 7.4)

0.156

Log P

0.156

Molar Refractivity

0.0

Polarizability

3.5074239

Polar Surface Area

0.0

Rotatable Bonds

Lipinski's Rule of Five

true

Acid pKa

3.09

Data Source

Commercial Catalog

Academic Data

Data Source

Names and Identifiers

IUPAC Traditional name

copper(1+) bromide λ¹-copper(1+) ion bromide

Synonyms

CUPROUS BROMIDECopper(I) bromideCopper(I) bromide, Puratronic®溴化亚铜(I)溴化亚铜(I), Puratronic®

IUPAC name

$l^{1}-copper(1+) ion bromide λ¹-copper(1+) ion bromide

Names and Identifiers

Registration numbers

CAS Number

EC Number

PubChem CID

PubChem SID

Merck Index

MDL Number

Registration numbers

Properties

Product Information

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98%

99.998% (metals basis)

Physical Property

4.98

Slightly soluble in cold water. Decomposes in hot water. Soluble in HBr, HCl, NH4OH

Powder

Powder, Ampouled under argon

1345°C

492°C

Properties

Related Proteins

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Molecular Spectra

No Data Available

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Molecule Details

MP Biomedicals

05214945

MP Biomedicals Rare Chemical collection

Molecule Details

References

PubChem Literature

From Data Sources

• Catalyst for 1,4-addition of Grignard reagents to enones: J. Org. Chem., 27, 707 (1962); Org. Synth. Coll., 8, 522 (1993).

• Reaction of Grignard reagents with aromatic nitriles is potentially a useful route to ketones via the imine. However, in the absence of a catalyst, reaction is generally very slow and gives indifferent yields. In the presence of CuBr, tert-butylmagnesium chloride reacts readily with benzonitrile to give tert-butyl phenyl ketone in 94% yield: J. Org. Chem., 52, 3901 (1987).

• Precursor of organocopper reagents. For reviews, see: Org. React., 22, 253 (1975); 41, 135 (1992); Synthesis, 63 (1972); Tetrahedron, 45, 349 (1989).

References

Bioactivity

PubChem BioAssay

Bioactivity

Data Source

Commercial Catalog

Academic Data

Names and Identifiers

IUPAC Traditional name

copper(1+) bromide λ¹-copper(1+) ion bromide

Synonyms

CUPROUS BROMIDECopper(I) bromideCopper(I) bromide, Puratronic®溴化亚铜(I)溴化亚铜(I), Puratronic®

IUPAC name

$l^{1}-copper(1+) ion bromide λ¹-copper(1+) ion bromide

Registration numbers

CAS Number

EC Number

PubChem CID

PubChem SID

Merck Index

MDL Number

Molecule Details

MP Biomedicals Rare Chemical collection

References

PubChem Literature

From Data Sources

• Catalyst for 1,4-addition of Grignard reagents to enones: J. Org. Chem., 27, 707 (1962); Org. Synth. Coll., 8, 522 (1993).

• Precursor of organocopper reagents. For reviews, see: Org. React., 22, 253 (1975); 41, 135 (1992); Synthesis, 63 (1972); Tetrahedron, 45, 349 (1989).

Bioactivity

PubChem BioAssay

Properties

Product Information

Download link

98%

99.998% (metals basis)

Physical Property

4.98

Slightly soluble in cold water. Decomposes in hot water. Soluble in HBr, HCl, NH4OH

Powder

Powder, Ampouled under argon

1345°C

492°C

Molecule

ID:110425