CAS 16949-15-8|LithoTab borohydride|LITHIUM BOROHYDRIDE|lithium(1+) ion boranuide|lithium(1+) ion boranuide|Lithium tetrahydroborate|lithium boranate|Lithium hydroborate|Borate(1-), tetrahydro-, lit...

General Information

Structure

Molecular Formula

BLi

Molecular Mass

17.752

Exact Mass

18.02530995

Charge

InChI

InChI=1S/BH4.Li/h1H4;/q-1;+1

InChIKey

UUKMSDRCXNLYOO-UHFFFAOYSA-N

Canonic Smiles

[Li+].[BH3-]

Isomeric Smiles

[Li+].[BH3-]

Calculated Properties

JChem

H Acceptors

H Donor

LogD (pH = 5.5)

0.0

LogD (pH = 7.4)

0.0

Log P

0.0

Molar Refractivity

0.0

Polarizability

1.7969184

Polar Surface Area

0.0

Rotatable Bonds

Lipinski's Rule of Five

true

Acid pKa

3.09

Data Source

Names and Identifiers

IUPAC Traditional name

LithoTab borohydride lithium(1+) ion boranuide

Synonyms

LITHIUM BOROHYDRIDELithium tetrahydroboratelithium boranateLithium hydroborateBorate(1-), tetrahydro-, lithiumLithium borohydride硼氢化锂Lithium borohydride solution硼氢化锂溶液Lithium tetrahydridoborate

IUPAC name

lithium(1+) ion boranuide

Names and Identifiers

Registration numbers

EC Number

CAS Number

MDL Number

PubChem CID

Wikipedia Title

Chemspider ID

PubChem SID

248537831620917242488221924853325

Merck Index

145525

Registration numbers

Properties

Related Proteins

No Data Available

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Molecular Spectra

No Data Available

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Molecule Details

Wikipedia

Lithium_borohydride

Sigma Aldrich

686026

Analysis Note
Hydrogen content, XRD plots and metal purity data are available upon request.
Packaging
10 g in glass bottle
Protocols & Applications
Metal Borohydrides as Hydrogen Storage Materials
Complex Hydrides: A New Category of Solid-state Lithium Fast-ion Conductors
Boron-based Hydrogen Storage

702714

Application
Material may form precipitate on standing, which does not affect its use
Reactant for:
• Preparation of gallium, indium, rhenium and zinc tris(mercaptoimidazolyl)hydroborato complexes1
• Mechano-chemical metathesis reactions2
• Noncatalytic hydrolysis for hydrogen generation3
• Growth of large gold monolayer protected-clusters4
• Anion substitution reactions5
• Dehydrogenation reactions6
Packaging
100, 800 mL in Sure/Seal™

222356

Packaging
1 g in glass bottle
10, 50 g in poly bottle
Application
Versatile reducing agent for aldehydes, ketones, acid chlorides, lactones, epoxides, and esters.1 Applied in the lithiation of 2H-WS2 giving high yields of exfoliated WS2, and opening the way to new intercalation compounds and nanocomposites.2

230200

Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
Packaging
4×10, 4×25, 100, 800 mL in Sure/Seal™
Application
Reactant for:
• Preparation of gallium, indium, rhenium and zinc tris(mercaptoimidazolyl)hydroborato complexes1
• Mechano-chemical metathesis reactions2
• Noncatalytic hydrolysis for hydrogen generation3
• Growth of large gold monolayer protected-clusters4
• Anion substitution reactions5
• Dehydrogenation reactions6

62460

Other Notes
Review1; Smooth reduction of esters2,3; Reduction of acids and other functional groups with LiBH4/Me3SiCl4
Packaging
5 g in glass bottle

Molecule Details

References

PubChem Literature

From Data Sources

• Monograph: J. Seyden-Penne, Reductions by the Alumino- and Borohydrides In Organic Synthesis, 2nd ed., Wiley, N.Y. (1997).

• Versatile reducing agent showing significant and useful differences from sodium borohydride. Review: Tetrahedron, 35, 567 (1979). For use in reduction of esters, see: J. Org. Chem., 47, 1604 (1982).

• Useful catalyst, in acetonitrile, for conversion of acid-sensitive aldehydes to 1,3-oxathiolanes and 1,3-dithiolanes: Synlett, 238 (2001).

• The combination of LiBH₄ and TMS chloride is a versatile, powerful reducing agent, which will reduce carboxylic acids, amino acids, amides, nitriles, etc: Angew. Chem. Int. Ed., 28, 218 (1989).

References

Bioactivity

PubChem BioAssay

Bioactivity