CAS 106-51-4|cyclohexa-2,5-diene-1,4-dione|Quinone|p-BENZOQUINONE|quinone|1,4-Benzoquinone|<i>p</i>-quinone|benzoquinone|<i>p</i>-benzoquinone|p-Benzoquinone|1,4-Benzoquinone|对苯醌|苯醌|p-Benzoquin...

Quinonep-BENZOQUINONE1,4-Benzoquinonep-quinonep-benzoquinonebenzoquinone1,4-Benzoquinonep-Benzoquinone对苯醌苯醌p-Benzoquinone1,4-Benzochinon2,5-Cyclohexadiene-1,4-dionep-Benzoquinone1,4-benzoquinone1,4-Benzoquinonebenzo-1,4-quinone1,4-benzoquinoneQuinonepara-benzoquinonep-quinonep-Chinonbenzoquinone

IUPAC Traditional name

quinone 1,4-benzoquinone

Names and Identifiers

Registration numbers

EC Number

203-405-2

CAS Number

106-51-4

PubChem SID

16209061524891552248475218143530

PubChem CID

Wikipedia Title

CHEMBL

KEGG ID

Chemspider ID

Unique Ingredient Identifier

3T006GV98U

CHEBI ID

16509CHEBI:15009CHEBI:8730CHEBI:12837CHEBI:49820CHEBI:18927CHEBI:16509

MDL Number

MFCD00001591

Beilstein Number

773967

Merck Index

148074

BRENDA Database

1.3.5.21.14.13.1671.16.3.11.3.5.61.1.1.955.3.1.13.4.24.691.1.1.3281.5.1.303.2.1.351.6.5.41.1.5.83.5.1.51.10.3.3

BRENDA Ligand Database

1674132591655205412235015910315

UniProt Database

C1EYZ6Q8D1V2B2I8R2Q9PET6Q1LU84A2BPP7Q81C25B2HV78B7JSX2Q6NA55Q7MBG6Q9Z9Q7Q9S3Q5Q735Z0B0BR13

ACToR Database

106-51-43225-29-4

PubMed Citation Links

113041271592075416484134104620552402381225057895151821981561823413956359118901

Protein Data Bank

6s823b6k6c854yqe6s3z7nnx

SABIO-RK Database

48671231914208107331514995881514686354853148012310

BKMS React Database

1655159101325916742350315205412

CompTox Database

DTXSID6020145

MetaboLights Database

MTBLS615MTBLS2878MTBLS1757MTBLS2279MTBLS601

MetaCyc Database

Reaxys Registry

SureChEMBL Database

Gmelin ID

Rhea Database

RHEA:60660RHEA:34327RHEA:23488

Patent number

WO2005044775US2006199242US2006084671US2002032189US2006057101US2008115296US2006195990GB2225781EP1341403US2007287672US2006156490EP1726589WO2007131286EP0819683

IEDB Database

UM-BBD compID

BindingDB Database

PDBeChem Database

IntEnz Database

EC 1.6.5.6EC 1.14.13.167

NMRShiftDB Database

10015929

EnzymePortal Database

C1I201

HMDB Database

HMDB0003364

Registration numbers

Properties

Pharmacology Properties

human ... ACHE(43), BCHE(590), CES1(1066)

Properties

Related Proteins

Related Proteins

Molecular Spectra

No Data Available

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Molecule Details

Purity: 98%

12309

Other Notes
Reagent for the spectrophotometric microdetermination of amines1

B10358

General description
Free radical inhibitor
Packaging
1 kg in glass bottle
5, 100, 500 g in glass bottle
Application
Dienophile employed in Diels-Alder cycloadditions to form naphthoquinones,1 and 1,4-phenanthrenediones.2

ChEBI

CHEBI:16509

The simplest member of the class of 1,4-benzoquinones, obtained by the formal oxidation of hydroquinone to the corresponding diketone. It is a metabolite of benzene.

Molecule Details

References

PubChem Literature

From Data Sources

• Reacts with allyl or isoprenyl tin derivatives in the presence of BF₃ etherate to give ortho allyl-substituted quinones: Org. Synth. Coll., 9, 741 (1998). For a reaction scheme, see 2,3-Dimethoxy-5-methyl-1,4-benzoquinone, B24777.

• Mild reoxidant in palladium-catalyzed reactions, to convert Pd(0) back to Pd(II); see e.g.: Org. Synth. Coll., 8, 137 (1993). For use in the Pd-catalyzed oxidative addition of amines to electron-deficient alkenes, to give enamines, see Palladium(II) chloride, 11034. For the cis-1,4-stereo- and regioselective chloroacetoxylation of 1,3-dienes by Pd(OAc)₂ and LiCl, in the presence of benzoquinone, see Palladium(II) acetate, 10516.

References

Bioactivity

PubChem BioAssay

Bioactivity

Molecule

ID:103047